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Lab. on Chemical Redox Acceleration Technologies for Water Quality



Journal
Simultaneous control of algal micropollutants based on ball-milled powdered activated carbon in combination with permanganate oxidation and coagulation | |
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Year of publication | 2020 |
Title of paper | Simultaneous control of algal micropollutants based on ball-milled powdered activated carbon in combination with permanganate oxidation and coagulation |
Author | Kangwoo Cho, Byung Min An, Soohyun So, Ana Chae, and Kyung Guen Song* |
Publication in journal | Water Research |
Status of publication | accepted |
Vol | 185 |
Link | https://www.sciencedirect.com/science/article/pii/S0043135420308009 1924회 연결 |
This study reports application of KMnO4 pre-oxidation and engineered powdered activated carbon (PAC) adsorption to simultaneously control geosmin, 2-methylisoborneol (2-MIB), and microcystin-LR (MC-LR) in conventional drinking water treatment plants (DWTPs). Pulverization of commercial wood-based PAC (1 mm ZrO2 ball, 12 h) reduced the median size to ~6 μm and resulted in overall enhanced kinetics for adsorption of the algal micropollutants. A series of parametric experiments were performed to estimate minimal contact for KMnO4 (1 mg L−1, 10 minutes) and PAC (20 mg L−1, 40 minutes) prior to coagulation, with the aim to meet guidelines (0.02, 0.02, and 1 μg L−1 for geosmin, 2-MIB, and MC-LR, respectively) at specific influent concentrations (0.1, 0.1, and 100 μg L−1) in surface water matrix. Ball-milling of parent PAC with a low oxygen content (~2.5 w/w%) could avoid interferences from/to the KMnO4 pre-oxidation and subsequent coagulation. Pilot-scale experiments confirmed the compatibility of the combined KMnO4 and PAC at existing DWTPs. |